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Cuscohygrine (along with the related metabolite hygrine) was first isolated by Carl Liebermann in 1889 as an alkaloid accompanying cocaine in coca leaves (also known as Cusco-leaves). Cuscohygrine is an oil that can be distilled without decomposition only in vacuum. It is soluble in water. It also forms a crystalline trihydrate, which melts at 40–41 °C. There are also the alkaloids ashwagandhine, ashwaganidhine, and somniferine, all of which have been identified exclusively in the ashwagandha plant itself. [ citation needed ]